问答题
From reactions(1)~(5)below,select,without any thermodynamic calculations those reactions which have:(a)large negative standard entropy changes,(b)large positive standard entropy changes,(c)small entropy changes which might be either positive or negative. (1)Mg(s)+Cl2(g)===MgCl2(s) (2)Mg(s)+I2(s)===MgI2(s) (3)C(s)+O2(g)===CO2(g) (4)Al2O3(s)+3C(s)+3Cl2(g)===2AlCl3(g)+3CO(g) (5)2NO(g)+Cl2(g)===2NOCl(g)
【正确答案】Solution: (1)large negative standard entropy changes:(1),(5). (2)large positive standard entropy changes:(4). (3)small entropy changes which might be either positive or negative(2),(3).