问答题 计算苯乙烯一丁二烯和苯乙烯一甲基丙烯酸甲酯的竞聚率。已知,对于丁二烯一苯乙烯,Q 1 =1,Q 2 =2.39,e 1 =一0.8,e 2 =一1.05;对于苯乙烯一甲基丙烯酸甲酯,Q 1 =1,Q 2 =0.74,e 1 =一0.8,e 2 =0.4。
【正确答案】正确答案:对于苯乙烯一丁二烯体系: r 1 =(Q 1 /Q 2 )exp[一e 1 (e 1 —e 2 )]一(1/2.39)exp[0.8(一0.8+1.05)]=0.511 r 2 =(Q 2 /Q 1 )exp[一e 2 (e 2 一e 1 )]=(2.39/1)exp[1.05(一1.05+0.8)]=1.84 对于苯乙烯一甲基丙烯酸甲酯体系: r 1 =(Q 1 /Q 2 )exp[一e 1 (e 1 -e 2 )]=(1/0.74)exp[0.8(一0.8—0.4)]=0.517 r 2 =(Q 2 /Q 1 )exp[—e 2 (e 2 -e 1 )]=(0.74/1)exp[一0.4(0.4+0.8)]=0.46
【答案解析】