问答题
计算苯乙烯一丁二烯和苯乙烯一甲基丙烯酸甲酯的竞聚率。已知,对于丁二烯一苯乙烯,Q
1
=1,Q
2
=2.39,e
1
=一0.8,e
2
=一1.05;对于苯乙烯一甲基丙烯酸甲酯,Q
1
=1,Q
2
=0.74,e
1
=一0.8,e
2
=0.4。
【正确答案】正确答案:对于苯乙烯一丁二烯体系: r
1
=(Q
1
/Q
2
)exp[一e
1
(e
1
—e
2
)]一(1/2.39)exp[0.8(一0.8+1.05)]=0.511 r
2
=(Q
2
/Q
1
)exp[一e
2
(e
2
一e
1
)]=(2.39/1)exp[1.05(一1.05+0.8)]=1.84 对于苯乙烯一甲基丙烯酸甲酯体系: r
1
=(Q
1
/Q
2
)exp[一e
1
(e
1
-e
2
)]=(1/0.74)exp[0.8(一0.8—0.4)]=0.517 r
2
=(Q
2
/Q
1
)exp[—e
2
(e
2
-e
1
)]=(0.74/1)exp[一0.4(0.4+0.8)]=0.46
【答案解析】