(46) {{U}}The determination of the sources of copper ore used in the manufacture of copper and bronze artifacts of Bronze Age civilizations would add greatly to our knowledge of cultural contacts and trade in that era when preliminary industry was on the horizon.{{/U}} Researchers have analyzed artifacts and ores for their concentrations of elements, but for a variety of reasons, these studies have generally failed to provide evidence of the sources of the copper used in the objects. Elemental composition can vary within the same copper-ore lode, usually because of varying admixtures of other elements, especially iron, lead, zinc, and arsenic. And high concentrations of cobalt or zinc noticed in some artifacts, appear in a variety of copper-ore sources. Moreover, the processing of ores introduced poorly controlled changes in the concentrations of minor and trace elements in the resulting metal. Some elements evaporate during smelting and roasting; different temperatures and processes produce different degrees of loss. (47) {{U}}Finally, flux, which is sometimes added during smelting to remove waste material from the ore, could add to the final product quantities of elements that are mixed together with copper.{{/U}}
An elemental property that is unchanged through these chemical processes is the isotopic composition of each metallic element in the ore. Isotopic composition, the percentages of the different isotopes of an element in a given sample of the element, is therefore particularly suitable as an indicator of the sources of the ore. (48) {{U}}Of course, for this purpose it is necessary to find an element whose elemental composition is more or less constant throughout a given ore body, but varies from one copper ore body to another or, at least, from one geographic region to another.{{/U}}
The ideal choice, when isotopic composition is used to investigate the source of copper ore, would seem to be copper itself. It has been shown that small but measurable variations occur naturally in the isotopic composition of copper. However, the variations are large enough only in rare ores; between samples of the common ore minerals of copper, isotopic variations greater than the measurement error have not been found. (49) {{U}}An alternative choice is lead, which occurs in most copper and bronze artifacts of the Bronze Age in amounts consistent with the lead being derived from the copper ores and possibly from the fluxes. {{/U}}The isotopic composition of lead often varies from one source of common copper ore to another, with variations exceeding the measurement error; and preliminary studies indicate virtually uniform is topic composition of the lead from a single copper-ore source. (50) {{U}}While some of the lead found in an artifact may have been introduced from flux or when other metals were added to the copper ore, lead so added in Bronze Age processing would usually have the same composition as the lead found in the copper ore.{{/U}} Lead isotope studies may thus prove useful for interpreting the archaeological record of the Bronze Age.