Copper ________ used by humans and is second only to iron in its utility through the ages.
句意: 古往今来, 铜是一个被人类使用, 并在效用上仅次于铁的金属。 copper是主语, and是平行结构的标志, 则划线处填谓语和宾语, 而其他选项均缺少谓语。