已知下列各物质在水溶液中的K_a :①K_HCN = 6. 2 x 10^-10;②K_HS = 7. 1x 10^-15，K_H2S = 1. 3 X 10^-7;③K_HF = 3. 5 x 10^-4;④K_HAc = 1. 8 x 10^-5。其中碱性最强的物质是