摘要
测定了过渡金属环戊二烯夹心化合物,(η^(5)-Cp)_(2)M(Cp=C_(5)H_(5),M=Mn,Fe,Ru)的红外与激光拉曼光谱,在此基础上,用G-F矩阵法计算了这类化合物的力常数.讨论了Cp-M化学键的性质.
On the basis of FT-infrared and Laser Raman spectra of(η^(5)-Cp)_(2)M(Cp=C_(5)H_(5);M=Mn,Fe,Ru)recorded,the force constants of given compounds have been calculated by G-F matrix program and the nature of Cp-M chemical bond have been discussed.
出处
《化学学报》
SCIE
CAS
1988年第2期131-136,共6页
Acta Chimica Sinica
基金
国家自然科学基金资助的课题
