摘要
Wearable triboelectric nanogenerators(TENGs)have attracted attention owing to their ability to harvest energy from the surrounding environment without maintenance.Herein,polyetherimide-Al_(2)O_(3)(PAl)and polyvinylidene fluoride-co-hexafluoropropylene(PVDF-HFP,PH)nanofiber membranes were used as tribo-positive and tribo-negative materials,respectively.Phytic acid-doped polyaniline(PANI)/cotton fabric(PPCF)and ethylenediamine(EDA)-crosslinked PAl(EPAl)nanofiber membranes were used as triboelectrode and triboencapsulation materials,respectively.The result showed that when the PAl-PH-based TENG was shaped as a circle with a radius of 1 cm,under the pressure of 50 N,and the frequency of 0.5 Hz,the open-circuit voltage(V_(oc))and short-circuit current(I_(sc))reached the highest value of 66.6 V and-93.4 to 110.1 nA,respectively.Moreover,the PH-based TENG could be used as a fabric sensor to detect fabric composition and as a sensor-inductive switch for light bulbs or beeping warning devices.When the PAl-PH-based TENG was shaped as a 5×5 cm^(2)rectangle,a 33 pF capacitor could be charged to 15 V in 28 s.Interestingly,compared to PAl nanofiber membranes,EPAl nanofiber membranes exhibited good dyeing properties and excellent solvent resistance.The PPCF exhibited<5%resistance change after washing,bending,and stretching.
基金
supported by the JSPS KAKENHI(Grant numbers JP20H00288 and JP22K02136)