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混合气体(H_2+CO)还原氧化铅的动力学研究

KINETICS OF REDUCTION OF LEAD OXIDE WITH(H_2+CO)MIXTURES
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摘要 本文采用等温热重法研究了混合气体(H_2+CO)还原氧化铅的速率过程。实验结果表明氧化铅的还原过程主要受界面反应控制,其表观活化能为108.25kJ/mol。当温度低于510℃时,混合气体(40%H_2+60%CO)的还原速率均比氢气或一氧化碳的还原速率快,这显示了混合气体低温还原氧化铅的优势。 In this paper the isothermal thermogravimetry was employed for in- vestigating the rate process of reduction of lead oxide with (H_2+CO) mixtures. The experimental results showed that the reduction process of lead oxide was essentially controlled by interfacial chemical reaction which apparent activation energy was 108.25 kJ/mol. When the temperature was below 510℃, the reduction rate of(40%H_2+60%CO)mixture was faster than both that of hydrogen and that of carbon monoxide, which implied advantages of lead ...
作者 陶东平
出处 《有色金属》 CSCD 1992年第1期73-76,14,共5页 Nonferrous Metals
关键词 氧化铅 还原动力学 混合气体 Lead oxide Kinetics of reduction Gas mixture
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