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碳纳米管对对硝基苯胺和N,N-二甲基苯胺的吸附 被引量:7

Adsorption of 4-Nitroaniline and N, N-dimethylaniline on Carbon Nanotubes
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摘要 测定了不同温度下碳纳米管对水溶液中对硝基苯胺和N,N-二甲基苯胺的吸附等温线,探讨了其吸附热力学特性和机理.研究结果表明:在实验范围内,碳纳米管对两种化合物的吸附都能较好的符合Freundlich模型,两种物质的吸附都是放热和熵减小的自发过程;吸附过程均具有物理吸附特征. The thermodynamic characteristics and mechanism of 4-nitroaniline and N, N-dimethylaniline adsorption by carbon nanotubes were studied and the adsorption isotherm line at different temperature were determined. The results showed that the adsorption of 4-nitroaniline and N, N-dimethylaniline accorded with Freundlich model well and that the adsorption is spontaneous, exothermic and decreasing entropy process. The process is physical adsorption.
出处 《华东师范大学学报(自然科学版)》 CAS CSCD 北大核心 2005年第Z1期138-142,共5页 Journal of East China Normal University(Natural Science)
基金 上海纳米科技专项基金(0252nm011)
关键词 碳纳米管 对硝基苯胺 N N-二甲基苯胺 吸附 机理 热力学 carbon nanotubes 4-nitroaniline N N-dimethylaniline adsorption mechanism thermodynamics
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