摘要
测定了不同温度下碳纳米管对水溶液中对硝基苯胺和N,N-二甲基苯胺的吸附等温线,探讨了其吸附热力学特性和机理.研究结果表明:在实验范围内,碳纳米管对两种化合物的吸附都能较好的符合Freundlich模型,两种物质的吸附都是放热和熵减小的自发过程;吸附过程均具有物理吸附特征.
The thermodynamic characteristics and mechanism of 4-nitroaniline and N, N-dimethylaniline adsorption by carbon nanotubes were studied and the adsorption isotherm line at different temperature were determined. The results showed that the adsorption of 4-nitroaniline and N, N-dimethylaniline accorded with Freundlich model well and that the adsorption is spontaneous, exothermic and decreasing entropy process. The process is physical adsorption.
出处
《华东师范大学学报(自然科学版)》
CAS
CSCD
北大核心
2005年第Z1期138-142,共5页
Journal of East China Normal University(Natural Science)
基金
上海纳米科技专项基金(0252nm011)
关键词
碳纳米管
对硝基苯胺
N
N-二甲基苯胺
吸附
机理
热力学
carbon nanotubes
4-nitroaniline
N
N-dimethylaniline
adsorption
mechanism
thermodynamics