摘要
Halfsandwich iron dicarbonyl complex [η 5-C5H3（t-Bu）2]Fe（CO）2Cl（1） reacts with 1, 2-dilithium diseleno carborane Li2Se2C2B 10H 10（2） to give a binuclear iron carborane complex [η 5-C5H3（t-Bu）2]2Fe2（CO）3·Se2C2B 10H 10（3）. The X-ray diffraction analysis of complex 3 reveals that one of the iron atoms is chiral.
Halfsandwich iron dicarbonyl complex [η 5-C_5H_3(t-Bu)_2]Fe(CO)_2Cl(1) reacts with 1, 2-dilithium diseleno carborane Li_2Se_2C_2B_ 10H_ 10(2) to give a binuclear iron carborane complex [η 5-C_5H_3(t-Bu)_2]_2Fe_2(CO)_3·Se_2C_2B_ 10H_ 10(3). The X-ray diffraction analysis of complex 3 reveals that one of the iron atoms is chiral.
基金
Supported by the National Natural Science Foundation of China( No.2 99740 2 9,2 992 5 10 1) and Special Funds forMajor State Basic Research Projects of China( G19990 64 80 0)
