An Efficient Mg/SmI_2 Catalytic System for the Intermolecular Deoxygenative Coupling of Amides and Ketones

An Efficient Mg/SmI_2 Catalytic System for the Intermolecular Deoxygenative Coupling of Amides and Ketones

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摘要 The intermolecular deoxygenative coupling of ketones with amides induced by Mg/SmI 2 catalyst was studied and a series of enamines was synthesized in moderate yields under mild and neutral conditions. The intermolecular deoxygenative coupling of ketones with amides induced by Mg/SmI 2 catalyst was studied and a series of enamines was synthesized in moderate yields under mild and neutral conditions.

作者许孝良张永敏

出处《Chinese Journal of Chemistry》 SCIE CAS CSCD 2002年第11期1463-1465,1136,共4页 中国化学（英文版）

基金 theNationalNaturalScienceFoundationofChina (No 2 0 0 72 0 33)andtheNaturalScienceFoundationofZhejiangProvince (No .2 980 6 7) ,China

关键词 magnesium samarium diiodide KETONE AMIDE ENAMINE magnesium, samarium diiodide, ketone, amide, enamine

分类号 O621.25 [理学—有机化学]

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Chinese Journal of Chemistry

2002年第11期

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An Efficient Mg/SmI_2 Catalytic System for the Intermolecular Deoxygenative Coupling of Amides and Ketones

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