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CYCLOPROPANATION OF ENAMINE AND ETHYL DIAZOACETATE CATALYZED BY COPPER COMPLEX 被引量:7

CYCLOPROPANATION OF ENAMINE AND ETHYL DIAZOACETATE CATALYZED BY COPPER COMPLEX
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摘要 The reaction of enamine with ethyl diazoacetate catalyzed by N-α-(4-chlorophenyl)-isobutyl (salicylaldimino) complex gives cyclopropantion product with a yield of about 12%. The reaction of enamine with ethyl diazoacetate catalyzed by N-α-(4-chlorophenyl)-isobutyl (salicylaldimino) complex gives cyclopropantion product with a yield of about 12%.
机构地区 Beijing Agr Univ
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1995年第7期557-558,共2页 中国化学快报(英文版)
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  • 7DOYLE M P, MCKERVEY M A, YET. Modern Catalytic Methods for Organic Synthesis with Diazo Compounds [ M]. New York:John Wiley and Sons, 1998.
  • 8WENKERT E, CPHERSON C A. Condensation of Acyldiazomethanes with Aldehydes, Ketones, and Their Derivatives [ J ]. J Am Chem Soc, 1972,94:8084-8090.
  • 9MUCK D L, WILSON E R. Synthesis and Nuclear Magnetic Resonance Snalysis of Cyclopropyl- and 1-bicyclo Alkylamines [J ]. J Org Chem, 1968,33:419-422.
  • 10HUISGEN R, REISSIG H U. Cycloaddition of a-diazo Carbonyl Compounds to Enamines [J]. Angew Chem Int Ed Engl, 1979,18:330-331.

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