Reaction of Substituted Cyclopentadienyl-magnesium-Chloride with Carbonyl Compound ( Ⅰ )——Reaction of (1, 1-Dialkyl-3-Butenyl) Cyclopentadienyl-magnesium-chloride with Ketones

Reaction of Substituted Cyclopentadienyl-magnesium-Chloride with Carbonyl Compound ( Ⅰ )——Reaction of (1, 1-Dialkyl-3-Butenyl) Cyclopentadienyl-magnesium-chloride with Ketones

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摘要 The substituted cyclopentadienyl-magnesium-chloride, obtained by exocyclic addition of 6,6-dialkylfulvene and allyl-magnesium-chloride, reacted with the ketone 3, the product was hydrolyzed and dehydrated to give the 2-(1 ,1-dialkyl-3-butenyl)-6,6-dialkyl-fulvene 5. The structure of 5 was determined by using the 1H NMR spectra of 5 and the adducts of 5 with tetracyanoethylene. The substituted cyclopentadienyl-magnesium-chloride, obtained by exocyclic addition of 6,6-dialkylfulvene and allyl-magnesium-chloride, reacted with the ketone 3, the product was hydrolyzed and dehydrated to give the 2-(1 ,1-dialkyl-3-butenyl)-6,6-dialkyl-fulvene 5. The structure of 5 was determined by using the 1H NMR spectra of 5 and the adducts of 5 with tetracyanoethylene.

作者 LI Ji-hai , LIU Jin-ting, JIAO Lun-ji, ZHANG Xiao-qing, MA Yu-dao and ZHANG Nan (Department of Applied Chemistry, Shandong University, Jinan, 250100)

出处《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1992年第4期370-376,共7页 高等学校化学研究（英文版）

基金 Supported by the National Natural Science Foundation of Shandong Province

关键词 Substituted cyclopentadienyl-magnesium-chloride Ketone FULVENE Substituted cyclopentadienyl-magnesium-chloride, Ketone, Fulvene

分类号 O6 [理学—化学]

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Chemical Research in Chinese Universities

1992年第4期

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Reaction of Substituted Cyclopentadienyl-magnesium-Chloride with Carbonyl Compound ( Ⅰ )——Reaction of (1, 1-Dialkyl-3-Butenyl) Cyclopentadienyl-magnesium-chloride with Ketones

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