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纳米TiO_2/CuO复合材料仿生合成及其光催化特性 被引量:3

Biomimetic synthesis of TiO_2/CuO nanocomposites and its photocatalytic properties
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摘要 以钛酸四丁酯为钛源,甘氨酸为模板剂,水热法合成纳米Ti O2/Cu O复合材料,采用XRD、SEM、FT-IR、XPS、UV-VIS DRS等分析手段对Ti O2/Cu O复合材料的晶型结构、形貌、粒径及组成进行表征。结果表明,XRD、SEM证实Ti O2/Cu O复合材料由锐钛矿型Ti O2和Cu O组成,形貌呈花瓣薄片状纳米花球,花瓣厚约15 nm;FT-IR、XPS表明其含有Ti—O键和Cu—O键,且Ti呈+4价、Cu呈+2价;UV-VIS DR显示其在紫外-可见光区具有显著的光吸收能力。相比P25型Ti O2,Ti O2/Cu O复合材料具有较好的光催化性能,光催化降解亚甲基蓝(MB)的效率高达85%。这可能由于Ti O2/Cu O复合材料具有宽的可见光区域和窄的带隙,以及Cu O对电子的捕获,促进了光生电子和空穴有效分离。 Ti O2/ Cu O nanocomposites were prepared by hydrothermal method using tetrabutyl titanate as the titanium source,glycine as the template. The samples were characterized by SEM,XRD,XPS,FT-IR,UV-VIS DRS and so on,analyzing its morphology,crystal structure and particle size composition,etc. The results indicated that nanoparticles were composed of anatase Ti O2 and Cu O,and the morphology was like Petals flaky nano ball,pwhose thickness was 15 nm. The data of FT-IR,XPS showed that it contained Ti—O bonds and the Cu—O bonds,while Ti was present + 4 valence and Cu was + 2 valence. The figure of UV-VIS DRS demonstrated that it had a significant light absorption capacity in its UV-visible region. Compared to with P25,Ti O2/ Cu O composite materials had good photocatalytic performance. The photocatalytic efficiency of nanocomposites for MB was as much as 85%. This may be due to the Ti O2/ Cu O composite materials with wide visible light region and narrow band gap,as well as the electronic capture of Cu O,promoting the photoproduction effective separation of electrons and holes.
出处 《环境工程学报》 CAS CSCD 北大核心 2015年第6期2783-2788,共6页 Chinese Journal of Environmental Engineering
基金 安徽省自然科学基金项目(1308085MC51) 安徽省高校自然科学基金重点项目(KJ2012A034) 全国大学生创新创业训练计划(201210363192) 全国大学生创新创业训练计划(201210363099)
关键词 仿生合成 纳米复合材料 TiO2前体 光催化性能 biomimetic preparation nanocomposites TiO2 precursor photocatalytic performance
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