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煤及其燃烧产物中无机组分分析方法比较 被引量:7

OPTION OF ANALYTICAL METHODS FOR INORGANIC CONSTITUENTS IN COAL AND ITS PRODUCTION OF COMBUSTION
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摘要 从三个方面对煤及其燃烧产物中无机组分的分析方法进行了比较和评价 :1 )比较和评价了煤及其燃烧产物中矿物分析方法 ,其中主要讨论了 XRD法和 CCSEM法 ;2 )比较和评价了煤及其燃烧产物中元素含量的分析方法 ,主要包括 X-射线和 v-射线技术 ;原子吸收或发射技术( AAS/ AES)和质谱法 ( MS) ;3)比较和评价了煤及其燃烧产物中微量元素的赋存形态分析方法 ,主要包括直接分析方法和间接分析方法 . In this paper, analytical methods for inorganics in coal are reviewed on three fronts which are methods for determining the mineralogy of coals,methods for determining elemental concentrations,and methods for determining modes of occurrence (speciation) of trace elements in coal. Accurate determinations of both association and coal mineralogy would lead to significant and much-needed refinements of models for the behavior of inorganics in both coal cleaning processes and coal combustion.Sample preparation and incremental enhancements will continue to be made in analytical methods for elemental concentrations.Regarding to the modes of occurrence of trace element ,there are mainly indirect and direct methods .
出处 《煤炭转化》 CAS CSCD 北大核心 2004年第3期6-11,22,共7页 Coal Conversion
基金 国家重点基础研究发展规划项目 ( 2 0 0 2 CB2 1160 2 ) 国家自然科学基金资助项目 ( 4 0 2 72 0 71)
关键词 煤及其燃烧产物 无机组分 分析方法 矿物 微量元素 赋存方式 coal and its production of combustion,inorganics,analytical methods,mineralogy, trace element,modes of occurrence
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  • 1Winburn R S,Grier D G,McCarthy G J et al. Rietveld Quantitative X-ray Diffraction of NIST Fly-ash Standard Reference Materials. Powder Diffr, 2000,15 : 163
  • 2Straszheim W E,Markuszewski R. Assessment of Coal Cleanability for Various Beneficiation Processes SEM-based Automated Image Analysis. Fuel Process Technol, 1990, 24:445-449
  • 3Straszheim W E,Markuszewski R. SEM-AIA Measurement of the Association of Mineral Matter with Organic Coal Matrix for Predicting Fine Coal Cleanability. Coal Prep, 1992,10: 59-62
  • 4Finkelman R B. The Inorganic Geochemistry of Coal:a Scanning Electron Microscopy View. Scanning Microsc,1988,2:97
  • 5Shirazi A R,Eklund L,Lundqvist O. Direct Quantitative Analysis of Mineral Matter and Different Forms of Pyritic Sulfur in Coal by Electron Probe Microanalysis (EPMA) and Automated Image Analysis (AIA). Fuel, 1994,73:193-199
  • 6Ikavalko E,Laitinen T,Revitzer H. Optimised Method of Coal Digestion for Trace Metal Determination by Atomic Absorption Spectroscopy. Fresenius J Anal Chem, 1999, 363:314
  • 7Querol X,Klika Z,Weiss Z et al. Determination of Element Affinities by Density Fractionation of Bulk Coal Samples. Fuel,2001,80:83
  • 8Swaine D J. Trace Elements in Coal Butterworths. London: [s. n. ], 1990
  • 9Conrad V B,Krofcheck D S. ICP-MS Determination of Trace Elements in Coal and Other Geological Materials. In:Vourvopoulos G ,Ed. Elemental Analysis of Coal and Its By-products. Singapore :World Scientific Press, 1992.97-99
  • 10Hickmott D D,Baldridge W S. Trace Element and S Iso-topic Microanalysis of Coal a Combined PIXE and SIMS Approach.In: Proc 8th Ann Int Pittsburgh Coal Conf, Univ Pittsburgh, 1991.148

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