摘要
J．H．范·佛里克-贝蒂(Van Vleck-Bethe)的晶场理论在物理、化学、矿物学等各个领域中取得了很大的成就。这个理论的特点是：当多电子体系的彻底量子力学计算难于进行时，把某些待算出的量作为由实验确定的经验参量处理，然后根据分子的点群对称性，用群论的方法以较少的参量把实验数据系统化，并且预测某些实验结果。
An empirical wave function of non-free Ou2+ is proposed on the basis of the distinction between free Cu2+ and non-free Cu2+,which permits the establishment of a quantitative correlation between the crystalline spectra and stereostructures of Cu2+-complexes.For the complexes of CuCl42-,CuCl43-,CuBr42-,CuBr53-,CuBr64-,Cu-O2(OH)2(H2O)2,Cu(H2O)4O2 and CuX4,theorical calculations are in good agreement with experimental results of crystalline spectra and stereostructures.
出处
《地球化学》
CAS
1979年第1期44-51,共8页
Geochimica
