期刊文献+

环境对AgTCNQ金属有机双层膜传质的影响 被引量:1

Influence of environment on transport behavior in Ag-TCNQ metal-organic thin film
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摘要  采用真空蒸发的方法交替沉积Ag和TCNQ分子制备了Ag TCNQ金属有机双层膜。研究了在大气,真空室,干燥器,饱和蒸汽室,水浸没5种不同环境下Ag TCNQ络合物形成过程中双层膜中的传质情况。结果显示氧气对传质过程基本无影响;而随着环境湿度的增加,传质速度显著加快,并采用一种电化学反应机制对这种加速现象做出了解释。 Ag-TCNQ thin films with different thickness were prepared by alternately vacuum depositing Ag and TCNQ. The transport in Ag-TCNQ thin films under different conditions was studied. The results showed that the transport process is accelerated with the increase of environmental humidity. A mechanism of electrochemistry is proposed to explain this phenomenon.
出处 《功能材料》 EI CAS CSCD 北大核心 2004年第5期593-594,597,共3页 Journal of Functional Materials
基金 上海市纳米专项资助项目(0259nm089) 国家自然科学基金资助项目(10374015) 国家重点基础研究发展计划(973计划)资助项目(2002CB613504)
关键词 金属有机双层膜 传质 湿度 电化学反应 Atmospheric humidity Electrochemistry Silver Thin films
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同被引文献15

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