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阴离子杂质对Ni(OH)_2电极性能的影响 被引量:2

The effects of anion impurities on the properties of Ni(OH)_2 electrode
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摘要 利用恒电流充放电和循环伏安测量技术,研究了电解液中添加F-、Cl-、Br-、CO2-3、SO42-等阴离子对氢氧化镍电极电化学性能的影响。结果表明:加入适量的Br-、SO42-能大幅度提高镍电极的还原电位和可逆性。 The effects of anion in electrolyte, such as F^-, Cl^-, Br^-, CO^(2-)_3,SO_4^(2-),on the electrochemical properties of the nickel hydroxide electrode were studied by constant current charge-discharge and cyclic voltammetry techniques. It was found that a certain contents of Br^- and SO_4^(2-) could improve the reduction potential of the electrode and the reversibility of the electrode reaction.
出处 《电池》 CAS CSCD 北大核心 2004年第4期261-262,共2页 Battery Bimonthly
基金 河北省自然科学基金资助项目(200006)
关键词 氢氧化镍电极 电解液 阴离子 循环伏安 Ni(OH)_2 electrode electrolyte anion cyclic voltammetry
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  • 1Gille G, Albrecht S, Meese-Marktschffel J, et al. Cathode materials for recharge able batteries-preparation, structure-property relationships and performance[J]. Solid State Ionics, 2002, 148(3- 4):269-282.
  • 2Chen J, Bradhurst D H, Dou S X , et al. Nickel hydroxide as an active material for the positive electrode in rechargeable alkaline batteries[J]. J Electrochem Soc, 1999, 146(10):3 606- 3 612.
  • 3Shukla A K, Venugopalan S, Hariprakash B. Nickel-based rechargeable batteries [J]. J Power Sources, 2001, 100(1-2):125 - 148.
  • 4董清海,颜广炅,余成洲,赖为华.电解液量对MH/Ni电池性能的影响[J].电池,2000,30(2):77-79. 被引量:5

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