摘要
本文报道室温固-固相化学反应一步法合成氨基酸铜配合物.trans-Cu(Gly)_2·H_2O、cis-Cu(Gly)_2·H_2O、trans-Cu(DL-Ala)_2、trans-Cu(DL-Ala)_2·H_2O、trans-Cu(DL-Val)和trans-Cu(DL-Leu)_2,经元素分析、IR、XRD、DTA测定,确定了配合物的组成及几何构型.并初步讨论了室温固相反应合成机理.
Six isomers of copper α-amino acids complexes [trams-Ou.(Gly)_2·H_2O, ois-Cu(Gly)_2·H_2O, trans-Cu (DL-Ala)_2, trams-Cu (DL-kla)_2·H_2O, trams-Ou (DL-Val)_2 and trans-Cu(DL-Leu)_2] have been synthesized by one step solid state reactions at room temperature. The composition and conformation of products are characterized by elemental analysis, IR, XRD and DTA. The reaction mechanism and the influence of trace H_2O on the solid state reaction have been discussed.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1993年第4期363-367,共5页
Acta Chimica Sinica
基金
国家自然科学基金
国家教委博士点基金
