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含双氨基硫脲支链结构荧光受体的合成及其阴离子识别研究 被引量：2

Fluorescent Receptor Containing Diaminothiourea Branches: Synthesis and Anion Recognition
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摘要 合成了一种新的具有双氨基硫脲侧链结构的荧光阴离子受体2,6 二(萘硫脲基氨甲酰基)吡啶,通过核磁共振氢谱、质谱、红外光谱等进行了结构表征,并用荧光光谱滴定法测定了该阴离子受体与不同阴离子的络合选择性.结果表明,该阴离子受体对AcO-具有较高的选择性和荧光响应,对不同阴离子的络合选择性次序为:AcO->p NO2C6H4OPO2-4 Cl-.3,H2PO- A novel fluorescent receptor was synthesized and characterized by ~1H NMR,MS,IR and Element Analysis. The binding properties for anions were studied by fluorescent titration method. The results show that the fluorescent receptor has a high selectivity and fluorescence responsibility to AcO^-. (It's) binding abilities to several anions follow the order: AcO^->p-NO_2C_6H_4OPO^(2-)_3,H_2PO^-_4Cl^-.
作者 隗兰华 吴严 王法军 孟令芝 何永炳
机构地区 武汉大学化学与分子科学学院
出处 《武汉大学学报（理学版）》 CAS CSCD 北大核心 2003年第6期709-712,共4页 Journal of Wuhan University:Natural Science Edition
基金 国家自然科学基金资助项目(20072029)
关键词 阴离子受体 合成 阴离子识别 双氨基硫脲侧链结构 荧光受体 荧光光谱滴定法 anion receptor synthesis anion recognition fluorescence
分类号 O626 [理学—有机化学] O657.3 [理学—分析化学]
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参考文献12

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共引文献6

同被引文献15

  • 1潘祖亭,余军平.荧光光谱法研究枸橼酸氯米芬与DNA的相互作用[J].武汉大学学报（理学版）,2004,50(4):407-410. 被引量：3
  • 2王法军,隗兰华,曾振亚,吴进龙,刘顺英,孟令芝,何永炳.含酰肼结构荧光受体的合成及其阴离子识别研究[J].武汉大学学报（理学版）,2003,49(6):713-716. 被引量：2
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二级引证文献5

武汉大学学报（理学版）
2003年 第6期

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