摘要
The crystal and molecular structures of Schiff base bis(salicylidene)-p-diaminobenzene were determined by X-ray crystallography. It crystallized in a monoclinic system with space group P2(1)/c, lattice parameters a=1.4649(3) nm, b=0.45770(9) nm, c=1.2241(2) nm, α=γ=90.00°, β=112.07(3)°, V=(0.7606(3) nm^3,) and Z=4. The crystal structure of the title compound is composed of discrete monomeric molecule of ((C_6H_4)(NCC_6H_4OH)_2) which is planar. The intermolecular hydrogen bonds make the compound steady.
The crystal and molecular structures of Schiff base bis(salicylidene)-p-diaminobenzene were determined by X-ray crystallography. It crystallized in a monoclinic system with space group P2(1)/c, lattice parameters a=1.4649(3) nm, b=0.45770(9) nm, c=1.2241(2) nm, α=γ=90.00°, β=112.07(3)°, V=(0.7606(3) nm^3,) and Z=4. The crystal structure of the title compound is composed of discrete monomeric molecule of ((C_6H_4)(NCC_6H_4OH)_2) which is planar. The intermolecular hydrogen bonds make the compound steady.
基金
Supported by the National Natural Science Foundation of China(No.2 0 2 75 0 2 0 ) the Natural Science Foundation ofShandong Province(No.Z2 0 0 2 B0 2 ) and the Outstanding Adult- young Scientific Research Encouraging Foundation of Shan-dong Provinc