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马尾松硫酸盐木浆活性氧漂白的研究 被引量:2

Totally Chlorine Free Bleaching with Dimethyldioxirane
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摘要 二甲基二环氧乙烷(DMD)脱木素率超过70%,白度达50%SBD以上,用DMD处理硫酸盐木浆所形成的残余木素能溶解于随后的碱抽提段,含有DMD(T)段的TEPQP漂序的硫酸盐木浆TCF漂白,其浆料白度可达90%SBD。 Dimethyldioxirane(T), as a source of “activated oxygen”, was tested. It may be used as a bleaching agent not containing any chlorine. A Kappa number reduction of more than 70% through a T stage bleaching was claimed for Masson pine kraft pulp. Dimethyldioxirane treatment renders the residual lignin soluble in the subsequent caustic extraction stage in a way much similar to the action of chlorine. Laboratory trials gave Masson pine kraft pulp of 90%SBD brightness via a totally chlorine free OTE PQP bleaching sequence.
出处 《中国造纸学报》 CAS CSCD 北大核心 1998年第B12期14-20,共7页 Transactions of China Pulp and Paper
基金 国家自然科学基金 广东省自然科学基金
关键词 木浆 氧漂 TCF漂白 残余木素 浆料白度 脱木素 溶解 硫酸盐 抽提 二甲基 dimethyldioxirane, delignify, totally chlorine free bleaching
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  • 1张巍,俞建勇,吴丽莉.竹纤维的DMD漂白工艺条件[J].纺织学报,2005,26(1):100-101. 被引量:3
  • 2黄干强,韩克涛,张曾,谢益民.DMD处理KP浆时残余木素结构的变化[J].中国造纸学报,1999,14(B10):36-43. 被引量:1
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  • 5Adam W, Chan Y Y, Cremer D, et al. Spectral and chemical properties of dimethyldioxirane as determined by experiment and ab initio calculations[J]. J Org Chem, 1987, 52(13): 2800-2803.
  • 6Adam W, Curci R, Edwards J O. Dioxiranes: Anew class of powerful oxidants[J]. American Chemical Society, 1989, 22(6): 205-211.
  • 7Argyopoulous D S, Sun Y, Berry R M, et al. Reactions of dimenthydioxirane with lignin model compounds[J]. Journal of Pulp and Paper Science, 1996, 22(3): J84-J90.
  • 8Ragauskas A J. Investigation of dimethyldioxirane as a bleaching reagent for kraR pulp[J]. Tappi Journal, 1993, 76(7): 87-90.
  • 9秦文娟,梁文芷.新漂剂-二甲基二环氧乙烷[J].纸和造纸,1997,7(4):10.
  • 10Gierer J. The reactions of lignins with oxygen-containing species[C]. Proceedings of the 7th International Symposium on Wood and Pulping Chemistry. Beijing: CTAPI, 1993, 1: 301-307.

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