摘要
系统介绍了α-烯烃的各种合成工艺,并对几种较先进的合成工艺作比较,认为美国Shell公司开发的SHOP法是目前生产α-烯烃较先进技术之一。介绍了α-烯烃的应用领域,尤其是用于聚乙烯共聚体的1-己烯和1-辛烯,用量最大。对α-烯烃的市场发展前景,从世界、国内分别作分析和展望,到2010年α-烯烃全球需求量将达6 840 kt;国内目前尚无1-己烯生产装置,认为1-己烯等α-烯烃共聚体已经成为我国聚烯烃发展的瓶颈。
Different synthesis processes of α- olefin were systematically introduced. Several advanced processes were compared. It is found that SHOP process developed by Shell is one of the best processes for producing α-olefins at present. The applications of α- olefin were described with the widest use of 1 - hexene and 1 - octene as comonomers for plolyethene. The markets of α - olefin at home and abroad were prospected. The global α - olefin will be needed in 6.84 million tons in 2010,but there is no plants for producing 1 - hexene at home,so α - olefin comonomers such as 1 - hexene will become bottleneck for developing our polyolefin industry.
出处
《精细石油化工进展》
CAS
2004年第11期12-16,共5页
Advances in Fine Petrochemicals
