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环四烯四胺-Ce(Ⅲ)金属配合物催化水解双(对硝基苯酚)磷酸酯 被引量：1

Study of the hydrolysis of bis(4-nitrophenyl)phosphate catalyzed by cyclotetraenetetraamine-Ce(Ⅲ)comples
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摘要 The hydrolysis of bis(4-nitrophenyl)phosphate(BNPP)catalyzed by cyclotetraenetetraamine-Ce(Ⅲ)complex was studied in this paper at 30℃ and pH7.2.The experimental results indicated that cyclotetraenetetraamine-Ce(Ⅲ)complex dramatically accelerated the hydrolysis of BNPP.The catatalytic mechanism was proposed in this paper and the kinetic mathematical model of the catalytic reaction was also developed according to the mechanism.The mixed system of cyclotetraenetetraamine-Ce(Ⅲ)complex and CTAB micelles inhibited the hydrolysis of BNPP,while the mixed system of cyclotetraenetetraamine-Ce(Ⅲ)complex and Brij35 micelles accelerated it. The hydrolysis of bis(4-nitrophenyl)phosphate(BNPP)catalyzed by cyclotetraenetetraamine-Ce(Ⅲ)complex was studied in this paper at 30℃ and pH7.2.The experimental results indicated that cyclotetraenetetraamine-Ce(Ⅲ)complex dramatically accelerated the hydrolysis of BNPP.The catatalytic mechanism was proposed in this paper and the kinetic mathematical model of the catalytic reaction was also developed according to the mechanism.The mixed system of cyclotetraenetetraamine-Ce(Ⅲ)complex and CTAB micelles inhibited the hydrolysis of BNPP,while the mixed system of cyclotetraenetetraamine-Ce(Ⅲ)complex and Brij35 micelles accelerated it.
作者 张元勤 熊俊如 刘凡 向清详
机构地区 乐山师范学院环境与生命科学系
出处 《化学研究与应用》 CAS CSCD 北大核心 2004年第6期811-813,共3页 Chemical Research and Application
基金 四川省科技厅(01GY051 63) 四川省教育厅(01LA52) 四川省乐山市科技局重点资助课题
关键词 金属配合物 磷酸酯 水解 金属胶束 metal complex organic phosphate hydrolysis metallomicelles
分类号 O643.321 [理学—物理化学]
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参考文献7

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同被引文献12

  • 1林竹修,黄生田,陈勇,胡伟,谢家庆,胡常伟,曾宪诚.两种双核配合物催化PNPP水解反应的机理研究[J].化学研究与应用,2004,16(4):475-478. 被引量：3
  • 2向清祥,夏传琴,余孝其,张丽群,谢如刚.大环多胺及其金属配合物的研究新进展[J].有机化学,2004,24(9):981-986. 被引量：28
  • 3Chin J,Banaszczyk M,Jubian V,et al.Cobalt (Ⅲ) complex-promoted hydrolysis of phosphate diesters:comparison in reactivity of rigid cis-diaquo(tetraaza) cobalt (Ⅲ)complexes[J].J Am Chem Soc.,1989,111 (1):186-192.
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  • 6Jurek P E,Jurek A M,Martell A E.Phosphate diester hydrolysis by mono-and dinuclear lanthanum complexes with an unusual third-order dependence[J].Inorg Chem.,2000,39 (5):1016-1020.
  • 7Hartshorn C M,Deschamps J R,Singh A,et al.Metal-chelator polymers as reactive adsorbents for organophosphate hydrolysis[J].React Funct Polym.,2003,55 (2):219-229.
  • 8Longhinotti E,Domingos J B,Szpoganicz B,et al.Catalytic effect of a dinuclear[Fe2Ⅲ(OH) (OH2)] complex in the hydrolysis of bis (2,4-dinitrophenyl) phosphate[J].Inorg Chim Acta,2005,358 (6):2089-2092.
  • 9Jiang W D,Xu B,Zhong J B,et al.Hydrolytic cleavage of bis(p-nitrophenyl) phosphate by Schiff base Mn(Ⅲ) complexes containing morpholine pendants in Gemini 16-6-16 micelles[J].J Chem Sci.,2008,120(4):411-417.
  • 10Tang S P,Zhou Y H,Chen H Y,et al.Ester Hydrolysis by a Cyclodextrin Dimer Catalyst with a Tridentate N,N',N"-Zinc Linking Group[J].Chem Asian J.,2009,8(4):1354-1360.

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化学研究与应用
2004年 第6期

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