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PMN-PZN-PZT四元系压电陶瓷材料的研究 被引量:3

Study of the PMN-PZN-PZT Quaternary Piezoelectric Ceramic Materials
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摘要 采用传统的氧化物混合烧结工艺制备了Pb(Mn1/3Nb2/3)x(Zn1/3Nb2/3)y(ZrzTi1z)1xyO3四元系压电陶瓷材料。研究了成分及预烧温度对该四元系材料组织结构与性能的影响规律。研究结果表明:随着Pb(Mn1/3Nb2/3)O3含量的增多,陶瓷的相结构由四方相转变为三方相,准同型相界位于0.025 PMN~0.075 PMN之间,且Pb(Mn1/3Nb2/3)O3增加至7.5 %(摩尔分数),可以同时提高机电耦合系数kp和机械品质因数Qm,使kp达到0.575,Qm达到1 621;提高预烧温度可以改善陶瓷的烧结特性,同时可以改善陶瓷的介电、压电性能。 Pb(Mn1/3Nb2/3)x(Zn1/3Nb2/3)y(ZrzTi1z)1xyO3quaternary piezoelectric ceramics were prepared by a conventional mixed-oxide process。The effect of the composition and calcining temperature on the microstructure and properties were studied。It was found that with an increase of Pb(Mn1/3Nb2/3)O3,the phase structure changed from tetragonal to rhombohedral and the proper amount of Pb(Mn1/3Nb2/3)O3 would improve elctromechanical coupling factor kp and mechanical quality factor Qm simultaneously,kp=0.575 and Qm=1 621 were achieved;the higher calcining temperature could improve the sintering characteristic and the electric properties.
出处 《电子元件与材料》 CAS CSCD 北大核心 2004年第12期17-19,共3页 Electronic Components And Materials
基金 航空基金资助项目(02G53044)
关键词 无机非金属材料 四元系压电陶瓷 微观结构 机电耦合系数 机械品质因数 inorganic non-metallic materials quaternary system piezoelectric ceramic microstructure elctromechanical coupling factor mechanical quality factor
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参考文献2

  • 1Yoo Juhyun,Lee Yongwoo,Yoon Kwanghee, et al.Microstructural, electrical properties and temperature stability of resonant frequency in Pb(Ni1/2W1/2)-Pb(Mn1/3Nb2/3)O3-Pb(Zr,Ti)O3 ceramics for high-power piezoelectric transformer[J].Jpn J Appl Phys,2001,40:3
  • 2Fan Hui-qing,Park Gun-tae,Choi Jong-jin, et al.Preparation and improvement in the electrical properties of lead-zinc-niobate-based ceramics by thermal treatments[J].J Mater Res,2002,17(1): 180-185.

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