摘要
测定了0.101MPa压力下乙酸甲酯-甲醇、乙酸甲酯-甲醇-乙酸钾及乙酸甲酯-甲醇-氯化锂体系汽液平衡数据。以Rousseau拟二元体系模型及Furter拟二元体系模型处理溶盐三元体系,并用Van Laar方程、Margules方程及Wilson方程关联无盐及两拟二元体系,得到了较好的结果。
The vapor-liquid equilibrium data under 0.101MPa pressure have been measured experimentally for methyl acetate-methanol, methyl acetate-methanol-potassium acetate and methyl acetate-methanol-lithium chloride systems. Ternary systems containing salt were treated with the pseudobinary model of Rousseau and the pseudobinary model of Furter. Systems without and with salt were correlated by Van Laar equation, Margules equation and Wilson equation; fairly good results were obtained.
出处
《石油化工》
CAS
CSCD
北大核心
1993年第7期444-450,共7页
Petrochemical Technology
关键词
乙酸甲酯
汽液平衡
甲醇
methyl acetate, vapor-liquid equilibrium, methanol, ternary systems containing salt