期刊文献+

锂离子电池有机电解液热稳定性研究 被引量:8

Research on thermal stability of organic electrolyte solutions for Li - ion batteries
下载PDF
导出
摘要 从有机电解液自身热稳定性以及电极/有机电解液相互作用的热稳定性两个方面综述了锂离子电池有机电解液的热稳定性;认为,正极/有机电解液的反应对锂离子电池安全性的影响是最主要因素。并分别从抑制LiPF6分解、使用不燃或阻燃溶剂阐述了改善有机电解液热稳定性的方法。 The thermal stability of organic electrolyte solution itself, and the thermal stability of the reactions between electrode and organic electrolyte solution were all reviewed. It's believed that, the effects of reactions between positive electrods and organic electrolytes on security of Li-ion battery are one of the important elements. The methods to improve the thermal stability of organic electrolyte solutions were also reviewed from the below: (1) reducing the decomposition of LiPF6, (2) applying nonflammable or flamma-bility-retarded solvent as cosolvents or additives.
作者 庄全超 武山
出处 《电池工业》 CAS 2004年第6期315-319,共5页 Chinese Battery Industry
关键词 锂离子电池 有机电解液 热稳定性 Li - ion batteries organic electrolyte solutions thermal stability
  • 相关文献

参考文献27

  • 1McBreen J,Lee H S,Yang X Q. Synthesis of a new family of fluorinated boronate compounds as anion receptors and studies of their use as additives in lithium battery electrolytes [A]. Proceedings on China International Battery Fair [C]. Beijing: Chinese Jou
  • 2Lee H S,Yang X Q,Xiang C L,et al. The sythesis of a new family of boron - based anion receptors and the study of their effect on ion pair dissociation and conductivity of lithium salts in nonaqueous solution[J] . J Electrochem Soc, 1998,145(8):2 813 -2 81
  • 3Wang, Yasukawa X E, Kisuya S. Nonflammable trimethyl phosphate solvent- containing electrolytes for lithium- ion batteries: Ⅱ. The use of an amorphous carbon anode[J] . J Electrochem Soc, 2001, 148(10): A1 066 -A1 071.
  • 4Richard M N, Dahn J R, Predicting electrical and thermal abuse behaviours of practical lithium- ion cells from accelerating rate calorimeter studies on small samples in electrolyte [J]. J Power Sources, 1999, 79:135 - 142.
  • 5Arai H, Tsuda M, Saito K, et al. Thermal reactions between delithiated lithium nickelate and electrolyte solutions[J] . J Electrochem Soc, 2002, 149: A 401 - A 406.
  • 6Zhang Z,Fouchard D,Rea J R. Differential scanning calorimetry material studies: implications for the safety of Li - ion cells [J]. J Power Sources, 1998, 70:16 -20.
  • 7Mcbreen J, Lee H S, Yang X Q,et al. New approaches to the design of ploymer and liquid electrolytes for lithium batteries [J]. J Power Sources, 2000, 89:163 - 167.
  • 8Tasaki K, Nakamura S. Computer simulation of LiPF6 salt association in Li- ion battery electrolyte in the presence of an anion trapping agent[J]. J Electrochem Soc, 2001, 148: A 984 - A 988.
  • 9Wilkinson David P, Dahn Jeffery R. Electrolyte solution sequestering agents for electrochemical cells having carbonaceous electrodes [ P]. USP: 5130211, 1992 - 07 - 14.
  • 10Aral, Juichi Higashiibaraki - gun, Ibaraki - ken. Lithium secondary battery and liquid electrolyte for the battery[P] .EP: 0 938 151A2,1999.

同被引文献40

引证文献8

二级引证文献48

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部