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稀土La^(3+)掺杂固体超强酸SO_4^(2-)/TiO_2催化合成二芳基乙烷的研究 被引量:12

Catalytic synthesis of diphenylethylane with solid superacid SO_4^(2-)/TiO_2 doped rare-earth lon La^(3+)
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摘要 The syntheis of diphenyletylane with xylol and styrene as reactants and solid superacid SO42-/TiO2 doped rare-earth metal ion La3+ as a catalyst was reported.The results showed that the optimal conditions were using 1% of catalyst with the molar ration of xylol to styrene being 7.5:1,at temperature of 140℃ for 3 h;The yield of diphenylethylane under such conditions was about 97.5%. The syntheis of diphenyletylane with xylol and styrene as reactants and solid superacid SO_4^(2-)/TiO_2 doped rare-earth metal ion La^(3+) as a catalyst was reported.The results showed that the optimal conditions were using 1% of catalyst with the molar ration of xylol to styrene being 7.5:1,at temperature of 140℃ for 3 h;The yield of diphenylethylane under such conditions was about 97.5%.
出处 《化学研究与应用》 CAS CSCD 北大核心 2005年第1期78-80,共3页 Chemical Research and Application
基金 山东省教育厅资助课题(JOOC54)
关键词 稀土离子 SO4^2-/TIO2 催化 合成 二芳基乙烷 rear earth ion SO_4^(2-)/TiO_2 catalysis synthesis diphenylethylane
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