期刊文献+

硝基苯类废水的预处理技术研究 被引量:13

Study on pre-treating methods of wastewater containing nitrobenzene
下载PDF
导出
摘要    Fe(OH)2对硝基苯具有强烈的还原作用,短时间内可把硝基苯还原为苯胺。催化铁屑法处理硝基苯类废水,除了包括铁屑法处理废水的各种反应外,还能使硝基苯在其表面直接还原,且反应在弱碱性条件下效果较好。m(Fe)∶m(Cu)为10∶1,pH为9.5,废水硝基苯进水质量浓度为250 mg/L,反应时间为30 min,硝基苯的去除率达100%。 Ferrous hydroxide is a strong reducing agent that can reduce nitrobenzene into aniline in a short time. Besides diverse chemical and electrochemical reactions in the iron scraps process, the direct electroreduction of nitrobenzene at the copper cathode is included in the iron scraps/copper process, and the effect of the reaction is better in alkaline medium. As a result, efficiency of nitrobenzene degradation still keeps at high level under this condition. The degradation efficiency of nitrobenzene reached 100% at 10∶1 weight proportion of copper to iron scraps, pH of 9.5 and 250 mg/l nitrobenzene, 30 min after the reaction.
出处 《环境污染与防治》 CAS CSCD 北大核心 2005年第1期8-11,共4页 Environmental Pollution & Control
基金 国家高新技术研究发展计划(863计划)研究课题"高级催化还原技术与设备"资助项目(No.2002AA601270)。
关键词 硝基苯类废水 铁屑法 去除率 预处理技术 苯胺 弱碱性 水质量 反应时间 催化 还原 Nitrobenzene Ferrous ions Iron scrap Catalyst Pre-treating
  • 相关文献

参考文献9

  • 1王咏梅,林朝阳,李克安,魏永巨,童沈阳.紫外光谱多元线性回归法同时测定硝基苯与亚硝基苯和苯胺[J].理化检验(化学分册),1997,33(1):16-17. 被引量:11
  • 2嵇雅颖,乌锡康,冯晓西.Fe^(2+)/Fe^(3+)系统处理邻、对硝基苯胺废水[J].上海环境科学,1998,17(9):14-16. 被引量:10
  • 3徐文英,周荣丰,高廷耀.催化铁内电解法处理难降解有机废水[J].上海环境科学,2003,22(6):402-405. 被引量:53
  • 4俞凌翀.基础理论有机化学[M].北京:人民教育出版社,1980..
  • 5Shriner R L, Fuson R C. The systematic identification of organic compounds. New York:John Wiley and Sons Inc., 1956.113~114?A?A
  • 6Klausen J,Trber S P,Haderlein S B,et al. Reduction of substituted nitrobenzenes by Fe(II)in aqueous mineral suspensions.Environ. Sci. Technol.,1995,29:2396~2404.
  • 7Agrawal A,Tratnyek P G. Reduction of nitro aromatic compounds by Zero-Valent iron metal. Environ. Sci. Technol.,1996,30:153~160.
  • 8Hung H M,Ling F H,Hoffmann M R. Kinetics and mechanism of the enhanced reductive degradation of nitrobenzene by elemental iron in the presence of ultrasound. Environ.Sci.Technol.,2000,34:1758~1763.
  • 9Klausen J,Ranke J ,Schwarzenbach R P. Influence of solution composition and column aging on the reduction of nitroaromatic compounds by Zero-Valent iron. Chemosphere,2001,44:511~517.

二级参考文献8

共引文献70

同被引文献1123

引证文献13

二级引证文献95

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部