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Kinetic parameters of oscillating reaction of amino acid-BrO3^- -Mn^2+-H2SO4-acetone system 被引量:5

Kinetic parameters of oscillating reaction of amino acid-BrO_3^-Mn^(2+)-H_2SO_(4-)acetone system
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摘要 The oscillating behavior of thirteen amino acids [leucine (Leu), threonine (Thr), arginine (Arg), lysine (Lys), histidine (His), alanine (Ala), glutamine (Glu), glycine (Gly), methionine (Met), cystine (Cys), tryptophan (Trp), serine (Ser) and tyrosine (Tyr)] in amino acid- BrO?3 -Mn2+- H2SO4-acetone system is studied by using a potentiometric determination. With the help of the oscillatory induction period and oscillation period obtained by the oscillating wave, and Arrhenius equation, the kinetic parameters [the appar- ent activation energy (E) and pre-exponential constant (A)] and rate constant (k) of the above-mentioned oscillating re- action are estimated. The oscillating behavior of thirteen amino adds [leucine (Leu), threonine(Thr), arginine (Arg), lysine (Lys), histidine (His), alanine (Ala), glutamine (Glu), glydne (Gly),methionine (Met), cystine (Cys), tryptophan (Trp), serine (Set) and tyrosine (Tyr)] in amino acid-BrOJ -Mn^(2+)-H_2SO_4-acetone system is studied by using a potentiometric determination. With thehelp of the oscillatory induction period and oscillation period obtained by the oscillating wave,and Arrhenius equation, the kinetic parameters [the apparent activation energy (E) andpre-exponential constant (A)] and rate constant (k) of the above-mentioned oscillating reaction areestimated.
出处 《Chinese Science Bulletin》 SCIE EI CAS 2005年第1期15-20,共6页
基金 the Natural Science Foundation of Shaanxi Province(Grant No.2002B22).
关键词 动力学参数 化学振荡 氨基酸 BrO3^ MN^2+ H2SO4 丙酮 封闭系统 速度常数 amino acids chemical oscillation closed system kinetic parameters rateconstant.
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