摘要
本文探讨了一种新型尾式卟啉5-对(4-(间-吡啶氧基)丁氧基]苯基-10,15,20三苯基卟啉(简称PyBPTPP)的合成路线,并以PyBPTPP 为配体合成了金属铁卟啉Fe(Ⅲ)PyBPTPPCl.通过元素分析、质谱、红外光谱、紫外可见光谱、核磁共振谱和热分忻等手段对上述化合物进行了表征.
A new tailed porphyrin which bears covalently attached a pyridine as aaxial ligand,5-[4-(m-pyridyloxy) butoxy] pheny1-10,15,20-triphenylporphyrin(PyBPTPP)and its iron coordination compound (FePyBPTPPCl) have been synthesizedand characterized by elementary analysis,mass spectra,ultraviolet and vissiblespectra,infrared spectra,proton nuclear magnetic resonance spectra,thermo-gravimetic analysis and differential thermal analysis.The synthetic routes of thisnew tailed porphyrin were also discussed
出处
《中山大学学报（自然科学版）》
CAS
CSCD
1993年第2期1-7,共7页
Acta Scientiarum Naturalium Universitatis Sunyatseni
基金
国家自然科学基金
关键词
尾式卟啉
金属卟啉
络合物
合成
tailed porphyrin
metalloporphyrin
heme
model of cytochrome P450
