摘要
对POCl3与对苯二酚缩合反应动力学进行了研究,对反应机理作了推测,提出了反应本征动力学方程。宏观动力学测定表明反应拟为一级,其表观活化能为86.2kJ/mol.
in this paper, the kinetics of condensation reaction of POCl_3 and hydroquinone is studied. The intrinsic kinetic equation is obtained. The experimental data show that the reaction is of first grade,with the apparent activation energy of 86.2 KJ/mol.
出处
《福州大学学报(自然科学版)》
CAS
CSCD
1994年第2期93-97,共5页
Journal of Fuzhou University(Natural Science Edition)