摘要
SiO_2粉末在非水高浓度聚合物溶液中的分散陈立富(厦门大学化学系,厦门,361005)关键词SiO_2,氢键,分散剂无机粉末(如碳,SiO2等)与高分子聚合物组成的复合材料可优化高聚物的导电性能、机械性能及化学稳定性等。一般来说,只有当非常细小的粉末...
The dispersion of silica in concentrated courtelle/DMF solution was studied(Courtelle is a copolymer of 94 mol%acrylonitrile and 6 mol%methyl acrylate). It is found that the agglomeration of silica is the combined results of surface energy and surface hydrogen bonding, The dispersibility of silica is markedly improved by the addition of 3-trimethoxysilyl propylmethacrylate(>1.2%). The improvement is believed to be caused by the chemical reaction between the silane and silanol groups on silica surface, reducing the concentration of hydrogen bonding, hence the attractive forces.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1994年第2期281-282,共2页
Chemical Journal of Chinese Universities