摘要
深入讨论了重铂族离子有效核电荷Ｚ及ｄ轨道能级分裂△＿０值高于轻铂族的原因。用文献中大量可比资料，再次论证重铂族配合物的热力学稳定性和动力学惰性高于轻铂族配合物。
The reason why the effective nuclear charges Z and and also the △values of d-orbital energy level split of the heavy platinum metal ions are higher than those of the light ones was further discussed.By utilizing a lot of comparable data the demonstration was made repeatedly that the thermodynamic stability and kinetic inertness of heavy platinum group metal coordination compounds are higher than those of the light ones.
出处
《贵金属》
CAS
CSCD
北大核心
1994年第3期1-7,共7页
Precious Metals
关键词
热力学性质
动力学
铂系元素
配合物
Platinum metal complex,Thermodynamic propcrties,Kinetics
