摘要
合成所得的邻香兰素(2-羟基-3-甲氧基苯甲醛)与邻苯二胺双Schiff碱Ni(Ⅱ)配合物的晶体[Ni(C_8H_7O_2)_2(C_6H_4N_2)]·H_2O,空间群P2_1/n,a=0.8854(2),b=1.9067(5),c=1.1807(4)nm;β=99.43(2)°;Z=4; 结构解析最后的偏正因子R=0.044,R_W=0.052.标题配合物的热分解反应动力学方程式为:dα/dt=A·e^(-E/RT)·(3/2)·(1-α)[-1n(1-α)]^(1/3);热分解反应动力学补偿效应表达式为:InA=0.1800E+0.0789.
The synthesis, crystal structure and thermoanalysis of 3-methoxysalicylaldehyde 1,2-diaminobenzene nickel (Ⅱ) complex, [ Ni(C8H7O2)2(C6H4N2)] · H2O, were reported in this paper. The complex lies in monoclinic, space group P21 / n with a = 0.8854(2), b= 1.9067 (5), c=1.1807(4)nm,β= 99.43(2)°, Z = 4, final R = 0.044, Rw = 0.052. Kinetic parameters were obtained from analysis of the TG, DTG curves by integral's method and differential's method. The possible reaction mechanism was suggested by comparision of the kinetic parameters. The kinetic equation may be expressed as:dα/dt = A · e-E/Rr·(3/2) ·(1-α)[-ln(1-α)]1/3The mathematical expression of the kinetic compensation effect of the thermal decomposition reaction had been obtained.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1994年第7期676-682,共7页
Acta Chimica Sinica
