摘要
［Ｌｎ（ＨＣＯＯ）＿３·ｐｈｅｎ·Ｃ＿２Ｈ＿５ＯＨ］［Ｌｎ＝Ｐｒ、Ｇｄ］的电子结构和化学键董南，朱龙观，蔡国强，吴念慈（杭州大学化学系杭州３１００２８）关键词：化学键，电子结构，ＩＮＤＯ，配合物［Ｌｎ（ＣＣｌ＿３ＣＯＯ）＿３·ｐｈｅｎ·Ｃ＿２Ｈ＿５Ｏ...
The electronic structure and chemical bonding of the title complexes have been studied by INDOprogram appling to the lanthanoid compounds.We excellently explained the complexes which are dimeric,Incoordinate bonds of Ln-O and Ln-N,5d orbitals of Ln have largest contribution in all valence orbitals of Lnand 4f orbitals have hardly contribution,The results indicated that phen is a weak basic ligand and HCOO￣(-) isaligand of strong coordinated ability.
出处
《化学研究与应用》
CAS
CSCD
1994年第1期67-71,共5页
Chemical Research and Application
基金
国家自然科学基金
关键词
化学键
电子结构
络合物
镨
钆
chemical bond
electronic structure
INDO
complex
