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嘧啶类液晶化合物的合成及性能研究 被引量:1

SYNTHESIS AND DETECTION OF LIQUID CRYSTALS OF THE PYRIMIDINE FAMILY
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摘要 设计并合成了2—(4’—烷氧基苯基)—5—烷基—嘧啶,2—(2’—氟—4’烷氧基苯基)—5—烷基嘧啶,2—(3—’氟—4’—烷氧基苯基)—5—烷基—嘧啶和2—(4’—烷基联苯基)—嘧啶等四类液晶化合物并测定比较了它们的相态和介电常数,电阻率等物理常数。 Four series of 2-biphenyl and 2-phenyl as well as 2-laterally monofluoro-substi-ituted phenyl pyrimidines were synthesized and their mesomorphic and some physical properties were investigated. They are relatively lowmelting point with transition phases of I -SA-Sc and wide-range Sc phase. The compounds with extra fluorine especially in 2’-position (2) have lower melting points and phase - transition temperature, dielectric anisotropies become negative. It also can be seen that compound 3 have much greater smectic tendencies (particuiarly Sc) , but smectio phase was almost disappeared in 2. These compounds have been used as excellent hosts materials for TN and FLC systems.
作者 龙玲 荣国斌
出处 《液晶通讯》 CAS 1994年第3期179-183,共5页
关键词 嘧啶类 液晶 化合物 性能 合成 Pyritnidine Liquid Crystal Synthesis
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  • 1刘鑫勤,任惜寒,尚洪勇,等.含有嘧啶环的端异硫氰基类液晶化合物及其制备方法:中国,CNl01580716[P].2009-11-18.
  • 2刘鑫勤,张建立,梁晓.一种2位含有乙炔基的嘧啶环类液晶化合物及其制备方法:中国,CN101323596[P].2008-12-17.
  • 3田博.嘧啶类液晶的合成与性质研究[D]//工程硕士论文,北京:清华大学,2008.
  • 4Boiler A,Cereghett M, Schadt M, et al. Synthesis and some physical properties of phenylpyrimidines [J]. Mol. Cry. Liq. Cryst. , 1977, 42:215-231.
  • 5Yoshida N, Ogawa T, Kitano K. Phenylpyrimidinecarboxylate derivatives and liquid-crystal compositions containing them:America, US4874546 [P]. 1989-10-17.
  • 6BollerA, Schadt M,Villiger A. Disubstituted pyrimidines: America, US4462923 [P]. 1984-07-31.
  • 7Malloy T P, Engel D J. 4-Vinylbenzeneacetic acid: America, US4499300 [P]. 1985-02-12.
  • 8Boller A,Cereghett M,Scherrer H. Phenylpyrimidine..Germany,DE2547737[P]. 1976-04-29.
  • 9董兆恒,刘骞峰,李启贵,王作全.对正烷基苯乙酸的合成[J].应用化工,2001,30(1):38-39. 被引量:5

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