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草酸根桥联的双核铜髤配合物[Cu_2(phen)_2(H_2O)_2(μ_2-C_2O_4)](NO_3)_2的合成及晶体结构 被引量:7

Synthesis and Crystal Structure of Oxalato-bridged Binuclear Copper(Ⅱ) Complex [Cu_2(phen)_2(H_2O)_2(μ_2-C_2O_4)](NO_3)_2
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摘要 A new binuclear copper(Ⅱ) complex, [Cu2(phen)2(H2O)2( μ2-C2O4)](NO3)2, has been synthesized and characterized by elemental analysis, IR and UV-Vis spectrum. Its crystal structure was determined by single crystal X-ray diffraction techniques. Crystal data: monoclinic, space group P21/c, a=0.712 21(8) nm, b=1.170 93(14) nm, c=1.783 7(2) nm, β=111.828(2)°, and V=1.380 8(3) nm3, Dc=1.769 Mg·m-3, Z=2, F(000)=744, R1=0.025 4, wR2=0.069 5, Gof=1.077, Δρ=328^-455 e·nm-3. The complex is packed by one centrosymmetry binuclear copper(Ⅱ) unit, oxalate dianion and NO3- anion. In the molecule structure of the title complex, two Cu(Ⅱ) ions are bridged by oxalate dianion and each Cu(Ⅱ) ions coordinates with two nitrogen atoms from 1,10-phenanthroline ligand and one oxygen atom from water to form a five-coordinate distorted square-pyramidal configuration. The hydrogen bonds are observed between coordinated water molecules and NO3- anions. The analysis of the crystal structure indicates that the complex has a two-dimensional stacking network structure, which is formed by intramolecular hydrogen bonds, intermolecular hydrogen bonds and stacking effect of aromatic ring. CCDC: 255345. A new binuclear copper(Ⅱ) complex, [Cu2(phen)2(H2O)2( μ2-C2O4)](NO3)2, has been synthesized and characterized by elemental analysis, IR and UV-Vis spectrum. Its crystal structure was determined by single crystal X-ray diffraction techniques. Crystal data: monoclinic, space group P21/c, a=0.712 21(8) nm, b=1.170 93(14) nm, c=1.783 7(2) nm, β=111.828(2)°, and V=1.380 8(3) nm3, Dc=1.769 Mg·m-3, Z=2, F(000)=744, R1=0.025 4, wR2=0.069 5, Gof=1.077, Δρ=328^-455 e·nm-3. The complex is packed by one centrosymmetry binuclear copper(Ⅱ) unit, oxalate dianion and NO3- anion. In the molecule structure of the title complex, two Cu(Ⅱ) ions are bridged by oxalate dianion and each Cu(Ⅱ) ions coordinates with two nitrogen atoms from 1,10-phenanthroline ligand and one oxygen atom from water to form a five-coordinate distorted square-pyramidal configuration. The hydrogen bonds are observed between coordinated water molecules and NO3- anions. The analysis of the crystal structure indicates that the complex has a two-dimensional stacking network structure, which is formed by intramolecular hydrogen bonds, intermolecular hydrogen bonds and stacking effect of aromatic ring. CCDC: 255345.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2005年第5期709-712,共4页 Chinese Journal of Inorganic Chemistry
关键词 双核铜(Ⅱ)配合物 草酸根桥联 晶体结构 complex analysis CRYSTAL CRYSTAL network NO3^- Cu(Ⅱ) 合成 UV-VIS and spect space group the The data unit with ATOM form one are new Its was ani IR oxalic acid binuclear copper(Ⅱ) complex crystal structure hydrogen bond stacking effect of aromatic ring
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