摘要
The complex(C24H24NO)2Cu·CH3CN（HL=S-（1-Benzy1-pyrrolidin-2-yl）-diphenyl-methanol）was （synthesized） by the electrochemical oxidation of Cu metal anodes in acetonitrile solution.The final product was （characterized） by elementary analysis,IR,and SEM and the structure was determined by single-crystal X-ray diffraction.The crystal belongs to trigonal,space group P3121 with a=9.8201（15）,b=9.82501（15）,c=36.516（6）?,α=β=90°,γ=120°,V=3049.6（8）?3,Z=3,ρcalc.=1.290g/cm3,F（000）=1251.In the complex two hydroxy oxygen atoms and two pyrrolidin nitrogen atoms from the ligand coordinate to copper（II）ion,forming a distorted square plane.
The complex(C_(24)H_(24)NO)_2Cu·CH_3CN(HL=S-(1-Benzy1-pyrrolidin-2-yl)-diphenyl-methanol)was (synthesized) by the electrochemical oxidation of Cu metal anodes in acetonitrile solution.The final product was (characterized) by elementary analysis,IR,and SEM and the structure was determined by single-crystal X-ray diffraction.The crystal belongs to trigonal,space group P3_121 with a=9.8201(15),b=9.82501(15),c=36.516(6)?,α=β=90°,γ=120°,V=3049.6(8)?~3,Z=3,ρ_(calc.)=1.290g/cm^3,F(000)=1251.In the complex two hydroxy oxygen atoms and two pyrrolidin nitrogen atoms from the ligand coordinate to copper(II)ion,forming a distorted square plane.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2005年第2期205-208,共4页
Chemical Research and Application
关键词
手性
电化学合成
晶体结构
chiral
electrochemical oxidation
crystal structure
