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界面活性剂对溴化锂吸收水蒸气的影响 被引量:4

Effects of Surfactants on Absorption of Water Vapor into Aqueous LiBr Solution
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摘要 为研究Marangoni效应的机理提供基础实验数据,同时也是为寻找更有效的添加剂以替代目前在溴化锂吸收式制冷机/热泵中被广泛采用的界面活性剂2-ethyl-1-hexanol和1-octanol,对一些可能成为界面活性剂的碳6和碳7的醇类物质开展了静态吸收促进实验研究。将碳6和碳7的醇,例如4-methyl-2-pentanol,2-ethyl-1-butanol,1-hexanol,2,4-dimethyl-3-pentanol,4-heptanol,2-heptanol和1-heptanol分别混合于62wt%浓度的溴化锂水溶液中,在静态池吸收器中来测试吸收水蒸气的情况。实验表明,在研究的实验条件下1-hexanol和1-hep-tanol对溴化锂水溶液吸收水蒸气的促进作用好于2-ethyl-1-hexanol。 The purpose of this study is to prepare some basic experimental data for mechanism study of Marangoni effect and to look for some more effective additives to substitute 2-ethyl-1-hexanol or 1-octanol which are widely used in lithium bromide absorption refrigeration system. In present study, absorption of water vapor into the 62 wt% lithium bromide solution with several six-carbon and seven-carbon alcohol additives such as 4-methyl-2-pentanol, 2-ethyl-1-butanol, 1-hexanol, 2,4-dimethyl-3-pentanol, 4-heptanol, 2-heptanol, and 1-heptanol were investigated by using a simple stagnant pool absorber. The results show that effects of 1-hexanol and 1-heptanol on absorption of water vapor into aqueous lithium bromide solution are better than those of 2-ethyl-1-hexanol.
出处 《制冷学报》 CAS CSCD 北大核心 2005年第2期29-33,共5页 Journal of Refrigeration
基金 国家自然科学基金资助项目(50476038)
关键词 界面活性剂 水蒸气 MARANGONI效应 溴化锂吸收式制冷机 溴化锂水溶液 实验数据 实验研究 醇类物质 实验条件 添加剂 吸收器 碳7 碳6 Thermal engineering,absorption mass,stagnant pool absorber,surfactant,lithium bromide/water
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参考文献4

  • 1Kashiwagi T, Kurosaki Y, Shishido H. Enhancement of vapor absorption into a solution using the Marangoni effect. Trans. JSME(1985), B51:1002-1009.
  • 2Hihara E, Saito T. Effect of surfactant on falling film absorption. Int. J. Refrig. 1993, 16:339-346.
  • 3Hoffmann L, Greiter I, Wagner A, et al. Experimental investigation of heat transfer in a horizontal tube falling film absorber with aqueous solutions of LiBr with and without surfactants. Int. J. Refrig. 1996, 19:331-341.
  • 4Glebov D, Setterwall F. Experimental study of heat transfer additive influence on the absorption chiller performance. Int J Refrig, 2002, 25:538-554.

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