摘要
富氮化合物是具有良好应用前景的烟火型气体发生剂原料,对具有含氮量高、热稳定性好和生成焓高的一些四唑、四嗪、呋咱类富氮化合物的合成方法及它们的性能进行了综述,重点描述了3,6二(1H1,2,3,4四唑5氨基)1,2,4,5四嗪(BTATZ)、3,3′偶氮双(6氨基1,2,4,5四嗪)(DAAT)、1,1′二甲基5,5′偶氮四唑(DMATZ)和3,6二(2H5四唑基)1,2,4,5四嗪(BTT)的合成路线。
Nitrogen rich compounds are promising materials for gas generating pyrotechnic compositions. The synthesis and properties of nitrogen rich compounds with high nitrogen content,good thermal stability and high formation enthalpy on the basis of tetrazole,tetrazine and furazan structures are reviewed. The synthetic routes of 3,6 bis(1H 1,2,3,4 tetrazol 5 yl amino) 1,2,4,5 tetrazine(BTATZ),3,3′ azobis(6 amino 1,2,4,5 tetrazine)(DAAT),1,1′ dimethyl 5,5′ azotetrazole(DMATZ) and 3,6 bis(2H 5 tetrazol yl) 1,2,4,5 tetrazine (BTT) are mainly discussed.
出处
《含能材料》
EI
CAS
CSCD
2005年第3期196-199,203,i004,共6页
Chinese Journal of Energetic Materials
关键词
有机化学
合成
综述
四唑
四嗪
氮杂环
气体发生剂
organic chemistry
synthesis
review
tetrazole
tetrazine
nitrogenous heterocyclic compound
gas generating composition
