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氧化石墨在H_2还原过程中的结构与性能变化 被引量:11

Changes of structures and properties of graphite oxide in process of reduction under H_2
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摘要 对氧化石墨进行了热解和H2还原处理,通过元素分析、X射线衍射分析、傅立叶变换红外光谱仪(FT IR)分析和粉末电阻率测定,初步探讨了氧化石墨的分子组成、官能团、晶体结构和电导率随还原温度的变化规律。结果表明:对经220℃热处理的热解氧化石墨进行H2还原处理时,随着还原温度的升高,还原氧化石墨中氧元素的质量百分含量减小,晶体结构逐渐回复为石墨的晶体结构,但存在明显的晶粒细化现象;随温度的升高,还原氧化石墨的电导率增大,并在500℃时达到最大值6.67S/cm;当还原温度超过500℃时,由于层间距增大及晶粒进一步细化,其电导率又逐渐降低;热解氧化石墨在H2中的还原过程可以分为两个阶段,第Ⅰ阶段主要发生—CO基团和C—OH基团的还原反应,第Ⅱ阶段残余的C—OH基团被还原。 Reduced graphite oxide at different temperatures was synthesized from graphite oxide by high temperature treatment and reduction under H_2. Composition, functional group, crystal structure and conductivities of reduced graphite oxide at different temperatures were investigated by elemental analysis, XRD, FT-IR and automatic multi-function resistivity measuring instrument. The results show that with the increasing of temperature oxygen content of pyrolytic graphite oxide at 220℃(PGO220) decreases. Although the grain is refined, the crystal structure is similar with that of graphite. The conductivity of reduction graphite oxide increases with the increasing temperature and at 500℃ it reaches the maximum, 6.67S/cm. when above 500℃ its conductivity decreases because of excursions and grain refining.There are two stages in the process of GO reduction. During the first stage —CO and C—OH are reduced, then the residual C—OH is reduced during the second stage.
出处 《中国有色金属学报》 EI CAS CSCD 北大核心 2005年第6期940-945,共6页 The Chinese Journal of Nonferrous Metals
基金 国家自然科学基金资助项目(50372019)
关键词 氧化石墨 还原 晶体结构 电导率 graphite oxide reduce crystal structure conductivity
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参考文献15

  • 1Hummers W S, Offeman Jr R E. Preparation of graphite oxide[J]. J Am Chem Soc, 1958, 80(2):1339.
  • 2Nakajima T, Mastsuo Y, Hagiwara R, et al. A new structure model of graphite oxide[J]. Carbon, 1988,26(3): 357 - 361.
  • 3Nakajima T, Mastsuo Y, Hagiwara R, et al. Formation process and structure of graphite oxide[J]. Carbon, 1994, 32(3): 469-475.
  • 4Mermoux M, Chabre Y, Rousseau A, et al. FTIR and 13C NMR study of graphite oxide[J]. Carbon, 1991,29 (3): 469 - 474.
  • 5Hontoria-Lucas C, Lopez-Peinddo A J. Study of oxygen-containing groups in a series of graphite oxides:physical and chemical characterization [J]. Carbon,1995, 33(11): 1585-1592.
  • 6Anton Lerf, Heyong Hee. Structure of graphite oxide revisited[J]. J Phys Chem, 1998, 102: 4477- 4482.
  • 7张海燕,何艳阳,薛新民,成晓玲,彭少麒.碳弧法中碳包Fe纳米晶及其相关碳微团的形成[J].无机材料学报,1999,14(2):291-296. 被引量:6
  • 8LI Xuan-ke, LEI Zhong-xing, REN Rong-cui, et al.Characterization of carbon nanohorn encapsulated Fe particles[J]. Carbon, 2003, 41(15): 3063-3074.
  • 9Cassagneau T, Fendler J H. Preparation and layer-by layer self-assembly of silver nanoparticles capped by graphite oxide nanosheets[J]. J Phys Chem B, 1999,103(11): 1789 - 1793.
  • 10LIU Ping-gui, GONG Ke-cheng. Synthesis of polyaniline-intercalated graphite oxide by an in situ oxidative polymerization reaction[J]. Carbon, 1999, 37(4): 701 - 711.

二级参考文献22

  • 1[1]Shioyama H. The interactions of two chemical species in the interlayer spacing of graphite[J]. Synth Met, 2000, 114: 1-15.
  • 2[5]He H Y, Klinowski J, Forster M, et al. A new structural model for graphite oxide[J]. Chem Phys Lett, 1998, 287(1): 53-56.
  • 3[6]Matsuo Y, Tahara K, Sugie Y. Structure and thermal properties of poly(ethylene oxide)-intercalated graphite oxide[J]. Carbon, 1997, 35(1): 113-120.
  • 4[7]Matsuo Y, Niwa T, Sugie Y. Preparation and characterization of cationic surfactant-intercalated graphite oxide[J]. Carbon, 1999, 37(6): 897-901.
  • 5[8]Matsuo Y, Tahara K, Sugie Y. Synthesis of poly(ethylene oxide)-intercalated graphite oxide[J]. Carbon, 1996, 34(5): 672-674.
  • 6[9]Matsuo Y, Hatasa K, Sugie Y. Preparation and characterization of poly(vinyl alcohol)- and Cu(OH)2-poly(vinyl alcohol)-intercalated graphite oxides[J]. Chem Mater, 1998, 10(8): 2266-2269.
  • 7[10]Kotov N A, Dekany I, Fendler J H. Ultrathin graphite oxide-polyelectrolyte composites prepared by self-assembly: transition between conductive and non-conductive states[J]. Adv Mater, 1996, 8(8): 637-641.
  • 8[11]Kyotani T, Moriyama H, Tomita A. High temperature treatment of polyfurfuryl alcohol/graphite oxide intercalation compound[J]. Carbon, 1997, 35(8): 1185-1187.
  • 9[12]Higashika S, Kimura K, Matsuo Y, et al. Synthesis of polyaniline-intercalated graphite oxide[J]. Carbon, 1999, 37(2): 354-355.
  • 10[13]Liu P, Gong K. Synthesis of polyaniline-intercalated graphite oxide by an in situ oxidative polymerization reaction[J]. Carbon, 1999, 37(4): 706-707.

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