摘要
用TG DTG技术研究了一水合草酸钾在静态空气中的热分解过程.根据TG曲线确定了热分解的中间产物及最终产物.运用Popescu的热分析动力学数据处理方法,确定了第1步和第2步热分解反应的动力学三因子,即表观活化能E、指前因子A和机理函数f(α).
The thermal decomposition of the potassium oxalate monohydrate in a static air atmosphere was investigated by TG-DTG techniques.The intermediate and residue for each decomposition were identified from TG curve.The kinetic triplet-the activation energy E,the pre-exponential A and the mechanism functions f(α) were obtained from analysis of the TG-DTG curves for thermal decomposition of the first stage and the second stage by the Popescu method.
出处
《河北师范大学学报（自然科学版）》
CAS
北大核心
2005年第4期376-379,共4页
Journal of Hebei Normal University：Natural Science
基金
河北省自然科学基金资助项目(202140)
河北省教育厅自然科学基金资助项目(2004325)
河北师范大学自然科学基金资助项目(L2001Y12)
