摘要
研究了在聚氯乙烯（ＰＶＣ）中，Ｓｂ＿２Ｏ＿３－ＺｎＳｎ（ＯＨ）＿６，Ｓｂ＿２Ｏ＿３－ＺｎＮＨ＿４ＰＯ＿４，ＺｎＳｎ（ＯＨ）＿６－ＺｎＮＨ＿４ＰＯ＿４二元体系的协同阻燃性能，以及Ｓｂ＿２Ｏ＿３－ＺｎＳｎ（ＯＨ）＿６－ＺｎＮＨ＿４ＰＯ＿４三元系的阻燃性能，采用混料回归实验设计，导出了三元系氧指数与阻燃剂含量关系的数学模型，经计算机计算并绘制出了氧指数等值图，该体系中Ｓｂ＿２Ｏ＿３－ＺｎＳｎ（ＯＨ）＿６，Ｓｂ＿２Ｏ＿３－ＺｎＮＨ＿４ＰＯ＿４复配具有正的协同作用，而ＺｎＳｎ（ＯＨ）＿６－ＺｎＮＨ＿４ＰＯ＿４复配则表现为负的协同作用。
The synergistic flame retardant properties of Sb2O3-ZnSn(OH)-6-ZnNH4PO4 andZnNH4PO4-ZnSn(OH)-6 binary systems and the flame retardant property of Sb-2O3-ZnSn(OH)-6-ZnNH4PO4 system in polyvinyl chloride(PVC)were studied in the paper,The mix-ture regression test was used to study the tri-ingredient system,and deduced a mathematicalmodel of the Limit Oxygen index(Io2)vs. content of flame retardant.An Oxygen Index e-qual value figure was calculated and made by computer. In the system,Sb2O3 and ZnSn(OH)6 have a great effect on flame retardant property of PVC,but ZnNH4PO4 has a slight ef-fect. The Sb2O3-ZnSn(OH)6 and Sb2O3-ZnNH4PO4 system exhibits positive synergism,butZnSn(OH)6.ZnNH4PO4 system shows negative synergism.
出处
《中南工业大学学报》
CSCD
1995年第6期744-748,共5页
Journal of Central South University of Technology(Natural Science)
基金
国家"八五"攻关资助项目
关键词
三氧化二锑
阻燃剂
聚氯乙烯
锡酸锌
磷酸铵锌
antimony trioxide
flame retardants
polyvinyl chloride /ZnSn(OH)6
ZnNH4PO4
oxygen index
