摘要
担载型铁金属簇催化剂催化ＣＯ_２加氢制低碳烯烃的研究黄友梅，翁善至，孟宪波，张传安（中国科学院兰州化学物理研究所，兰州７３００００）关键词低碳烯烃，ＣＯ_２加氢，担载型铁金属簇催化剂近年来，储量极丰富而又极便宜的二氧化碳重新引起世界各国科学家的兴趣，我...
Catalytic synthesis of light olefins from CO_2hydrogention over supported iron cluster catalysts was studied in a fixed-bed flow microreactor under atmospheric pressure.The results indicate that Fe_3/ZSM-5 catalyst exhibited a very high selectivity of 96.6% for C_2-C_3olefins and ethylene was almost the exclusive product (9 5.6%).Characterisation of the catalysts has been carried out using Mossbauer spectroscopy,transmission electron microscopy(TEM)and ultraviolet diffuse reflectance spectroscopy(UV-DRS).The observed high selectivities for light olefins appear to result from the existence of iron cluster structure on the surface of Fe_3/ZSM-5 catalysts.
出处
《分子催化》
EI
CAS
CSCD
1995年第1期78-80,共3页
Journal of Molecular Catalysis(China)
