摘要
本文利用紫外-可见吸收光谱法、顺磁共振(ESR)法系统地研究了多甲川键菁染料光氧化反应机理,结果表明,单线态氧( ̄1O_2)、超氧阴离子是导致染料光褪色的主要因素,而在没有氧气存在下,Dye ̄-也促使染料光褪色。
In this paper, the photcoxidation mechanisms of polymethylene chain cyanine dyes were studied by U-V spectroscopy and Electron Spin Resonance (ESR). It was revealed that singlet oxygen ( ̄1O_2)、 superoxide were the main factors causing the photofading of dyes ,and dye would cause the photofading of dyes without oxygen.
出处
《感光科学与光化学》
CSCD
1995年第2期136-143,共8页
Photographic Science and Photochemistry
基金
国家自然科学基金
关键词
多甲川键菁
染料
光氧化
增感染料
感光材料
polymethylene chain cyanine dye,photooxidation, singlet oxygen,superoxide To whom correspondence should be addressed.