摘要
两种C_(60)-甘氨酸酯衍生物的室温荧光光谱周德建,甘良兵,谭海松,骆初平,姚光庆,黄春辉(北京大学稀土材料化学及应用国家重点实验室,北京,100871)关键词C_(60)-甘氨酸酯衍生物,浓度猝灭,荧光寿命C60在低温或室温及在紫外或可见光的激发下...
Two new C_(60)-glycine ester derivatives C_(60)(EtOOCCHNHCHCOOEt)(A) and C_(60)(PbCH_2OOCCHNHCHCOOCH_2Ph)(B) were synthesized and purified. Their room temperature photoluminescence was measured for the first time from their CHCl3 solutions.It was first observed for fullerenes that their fluorescence could be quenched by concentration. The fluorescence lifetime was determined to be 1.5±0.3 ns for sA and 1.6±0.3 ns for B, respectively, using the frequency-domain method.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1995年第10期1512-1513,共2页
Chemical Journal of Chinese Universities
基金
国家攀登计划
国家自然科学基金
关键词
甘氨酸酯衍生物
荧光光谱
碳60
C_(60)-Glycine ester derivative, Concentration quenching, Fluorescence lifetime