摘要
甲基丙烯酸－Ｎ，Ｎ－二甲氨基乙酯及其聚合物的热和ｐＨ响应性陈双基，薛梅，李福绵（北京大学分校化学系北京１０００８３）（北京大学化学系北京１００８７１）关键词聚（甲基丙烯酸－Ｎ，Ｎ－二甲氨基乙酯），热响应性，ｐＨ响应性，功能高分子材料近年来，关于热响应...
Dimethylaminocthyl methylacrylate (DMAEMA) and its polymer exhibit thermo-sensitive response. The phase separation of their aqueous solution occurs abfruptly when the raising temperature reachs certain degrees. Thus, the temperature of phase separation of 10%,5.0%,2.5%,1.0%(DMAEMA) solution are 40.2,42.5,44.5,52.4℃ respectively. The thermosensitive phase separation also depends on the acidity of solution. The temperature and pH dependence swelling behavior o f slightly crosslinked P(DMAEMA) in water was studied. The adsorption of methyl orange for P(DMAEMA) at different temperature was investigated. P(DMAEMA) can lie expected as a functional material with thermal and pH-response.
出处
《高分子学报》
SCIE
EI
CAS
CSCD
北大核心
1995年第3期373-376,共4页
Acta Polymerica Sinica
关键词
热响应性
PH响应性
聚合物
DMAEMA
Poly (dimethylaminoethyl methacrylate), Thermo-response, pH-response, Functinoal polymer material
