摘要
本文对二环戊二烯基二羰基钛(1),的化学作了较详细的评述。第一部分叙述了合成1的多种不同方法及其结构和性质。第二部分详述了1的各种反应,包括铁金属价态变化的反应和钛价不变的反应。同时也涉及近年来1和其他类型金属有机化合物生成多核金属有机化合物或簇合物的反应。最后还讨论了1对无机小分子的活化反应。
This paper reviews the chemistry of bis (cyclopentadicnyl) dicarbonyl titanium (1), in details. In the first part, we describe the various synthetic methods of l as well as its structure and properties. In the second part, we describe the various reactions of 1 in- cluding the reactions of 1 accompanied by the valence change of titanium in 1 and the reac- tions of | keeping the valence of Ti unchanged. We also describe the recently developed reac- tions of other organometallic compounds with 1 forming multinuclear organometallic com- pounds or clusters and the reactions of the inorganic small molecular with 1.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1989年第4期311-320,共10页
Chinese Journal of Organic Chemistry
关键词
金属羰基化物
有机钛化合物
催化
metal carbonyl
organotitanium compound
bis(cyclopentadienyl) dicarbonyl titanium
cyclopentadiene
catalysis
