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脉冲CO色谱法测定铜催化剂的活性表面积 被引量:1

Determination of active surface areas of copper-containing catalysts by pulse CO chromatography
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摘要 介绍了用CO作吸附质,在室温下脉冲吸附测定铜催化剂中活性铜表面积的方法。试验结果表明,在不同载气中进行CO吸附,所得吸附量略有差异,He载气中测得结果略高于H2载气中测得的结果。结果还表明,本方法重复性好,相对误差在5%以内,可以作为快速评选催化剂的有效方法。 A determination method of active surface areas of copper-containing catalysts by pulse adsorption at an ambient temperature with CO as adsorbate is described in the present paper.The experimental results show that the obtained adsorbances are slightly different when CO adsorption is conducted in various carrier gases. The determined data for He carrier gas is slightly higher than that for H2 carrier gas.The results also show that the method has agood reproductivity and the relative error is within 5%, which can be used as an effective method for fast evaluation and selection of catalysts.
作者 刘仲堪
出处 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 1995年第5期24-27,共4页 Natural Gas Chemical Industry
关键词 催化剂 活性表面积 一氧化碳 脉冲CO色谱法 copper-containing catalyst,active surface area, adsorbate, CO
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参考文献1

  • 1程凤英,汤承璟.催化剂中铜表面积的测定及其与催化活性的关联[J]石油化工,1985(02).

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